(eta3-Allyl-2kappa3C)(chloro-1kappaCl)(micro-N,N'-diethyldithioxamidato-1:2kappa4S,S':N,N')[diphenyl(2-pyridyl)phosphine-1kappaP]palladium(II)platinum(II) chloroform solvate

Giuseppe Bruno; Santo Lanza; Francesco Nicoló; Giuseppe Tresoldi; Giuseppe Rosace

doi:10.1107/s0108270102006303

(eta3-Allyl-2kappa3C)(chloro-1kappaCl)(micro-N,N'-diethyldithioxamidato-1:2kappa4S,S':N,N')[diphenyl(2-pyridyl)phosphine-1kappaP]palladium(II)platinum(II) chloroform solvate

Acta Crystallogr C. 2002 May;58(Pt 5):m316-8. doi: 10.1107/s0108270102006303. Epub 2002 Apr 30.

Authors

Giuseppe Bruno¹, Santo Lanza, Francesco Nicoló, Giuseppe Tresoldi, Giuseppe Rosace

Affiliation

¹ Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Universitá degli Studi di Messina, Via Salita Sperone 31, I-98166 Vill. S. Agata, Messina, Italy.

PMID: 11983979
DOI: 10.1107/s0108270102006303

Abstract

The title compound, [PdPtCl(C(3)H(5))(C(6)H(10)N(2)S(2))(C(17)H(14)NP)].CHCl(3), was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd(eta(3)-C(3)H(5))(micro-Cl)](2). Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2) degrees. The dithioxamide bis-chelating bridge is flat.