Changes occurring in phenolic compounds and alpha-tocopherol of virgin olive oil during storage

J Agric Food Chem. 2002 Feb 27;50(5):1077-80. doi: 10.1021/jf010895e.

Abstract

Changes occurring in the concentrations of alpha-tocopherol, total phenols, and complex phenols linked to 3,4-dihydroxyphenylethanol (fractions FII and FIV) and p-hydroxyphenylethanol (FIII) during storage of virgin olive oil under environmental conditions were studied. Under diffused light, alpha-tocopherol was decomposed by 79% in 4 months, whereas <45% of the phenols were lost during the same period. Among the phenols, FII showed the least stability, and decreased by 72% in 6 months. Total phenols, FIII, and FIV recorded reductions in the range of 57-63% in 6 months. When the oil was stored in the dark, alpha-tocopherol, total phenols, FIII, and FIV exhibited similar profiles of degradation, reducing by 39-45% in the first 6 months and 50-62% in 12 months. FII was the least stable compound in the dark and recorded a loss of 64% in 6 months and 79% in 12 months. The levels of the above antioxidants were further related to peroxide formation. Remaining levels of these compounds at PV = 20 meq/kg ranged between 50 and 73% under diffused light and between 40 and 62% in the dark.

MeSH terms

  • Antioxidants / analysis*
  • Drug Stability
  • Food Handling
  • Food Preservation*
  • Light
  • Olive Oil
  • Peroxides / analysis
  • Phenols / analysis
  • Phenols / chemistry*
  • Plant Oils / chemistry*
  • Time Factors
  • alpha-Tocopherol / analysis
  • alpha-Tocopherol / chemistry*

Substances

  • Antioxidants
  • Olive Oil
  • Peroxides
  • Phenols
  • Plant Oils
  • alpha-Tocopherol