[2,6-Bis(isopropylthiomethyl)phenyl-kappa3S,C1,S']bromopalladium(II)

John Bacsa; Richard M Moutloali; James Darkwa

doi:10.1107/s0108270101020182

[2,6-Bis(isopropylthiomethyl)phenyl-kappa3S,C1,S']bromopalladium(II)

Acta Crystallogr C. 2002 Feb;58(Pt 2):m109-10. doi: 10.1107/s0108270101020182. Epub 2002 Jan 23.

Authors

John Bacsa¹, Richard M Moutloali, James Darkwa

Affiliation

¹ Department of Chemistry, University of Cape Town, Rondebosch 7700, South Africa. xrayjohn@psipsy.uct.ac.za

PMID: 11828096
DOI: 10.1107/s0108270101020182

Abstract

The title compound, [PdBr(C(14)H(21)S(2))] or [PdBr[C(6)H(3)(CH(2)S(i)Pr)(2)-2,6]], exhibits square-planar geometry at the Pd centre, with three atoms of the square plane provided by the rigid thiopincer ligand, i.e. 1,3-bis(thiomethyl)benzene.