Time-resolved laser spectroscopy of multiply ionized atoms: natural radiative lifetimes in Ce IV

Phys Rev Lett. 2001 Dec 31;87(27 Pt 1):273001. doi: 10.1103/PhysRevLett.87.273001. Epub 2001 Dec 10.

Abstract

Radiative lifetimes have been measured for two excited levels of Ce IV using the time-resolved laser-induced fluorescence technique. Ce3+ ions were produced in a laser-induced plasma. In the measurements, a suitable magnetic field was applied to reduce the recombination between electrons and the ions and thus the background light from the recombination, and special care was exercised to avoid flight-out-of-view effects on the lifetime measurements for the high-velocity ions. The experimental lifetime results, tau = 30(2) ns for the level 49 737 cm(-1) and tau = 30(3) ns for the level 52 226 cm(-1), were compared with relativistic Hartree-Fock calculations (tau = 30.5 and 30.0 ns) indicating a particularly excellent agreement.