Preparation, single-crystal X-ray diffraction and high-resolution NMR spectroscopic analyses of N-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl) trimethylammonium bromide

E Skorupowa; M Kurszewska; A Konitz; W Wojnowski; A Wiśniewski

doi:10.1016/s0008-6215(01)00037-4

Preparation, single-crystal X-ray diffraction and high-resolution NMR spectroscopic analyses of N-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl) trimethylammonium bromide

Carbohydr Res. 2001 Apr 12;331(3):343-6. doi: 10.1016/s0008-6215(01)00037-4.

Authors

E Skorupowa¹, M Kurszewska, A Konitz, W Wojnowski, A Wiśniewski

Affiliation

¹ Department of Chemistry, Gdańsk University, Poland.

PMID: 11383905
DOI: 10.1016/s0008-6215(01)00037-4

Abstract

Preparation of N-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)trimethylammonium bromide as the unique N-glycosylated quaternary salt derived from trialkylamine is described. The structure of the compound was elucidated by 1H and 13C NMR spectroscopy and by single-crystal X-ray analysis as well.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Anti-Infective Agents / chemistry*
Crystallization
Crystallography, X-Ray
Magnetic Resonance Spectroscopy
Molecular Structure
Monosaccharides / chemistry*
Quaternary Ammonium Compounds / chemistry*

Substances

Anti-Infective Agents
Monosaccharides
N-(2,3,4,6-tetra-O-acetyl-glucopyranosyl) trimethylammonium bromide
Quaternary Ammonium Compounds