Preparation, chemical and crystal structures of N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)pyridinium chloride

B Dmochowska; D Bednarczyk; A Nowacki; A Konitz; W Wojnowski; A Wiśniewski

doi:10.1016/s0008-6215(00)00215-9

Preparation, chemical and crystal structures of N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)pyridinium chloride

Carbohydr Res. 2000 Nov 17;329(3):703-7. doi: 10.1016/s0008-6215(00)00215-9.

Authors

B Dmochowska¹, D Bednarczyk, A Nowacki, A Konitz, W Wojnowski, A Wiśniewski

Affiliation

¹ Department of Chemistry, University of Gdańsk, Poland.

PMID: 11128599
DOI: 10.1016/s0008-6215(00)00215-9

Abstract

Preparation and isolation of N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)pyridinium chloride are described. Its structure was determined by 1H NMR spectroscopy and X-ray analysis. X-ray crystallography revealed that the salt crystallizes with one molecule of water. Ab initio calculations were used to determine charges on atoms in the cation of the title compound.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Glycosides / chemical synthesis*
Glycosides / chemistry*
Magnetic Resonance Spectroscopy
Molecular Structure
Monosaccharides / chemical synthesis*
Monosaccharides / chemistry
Pyridinium Compounds / chemical synthesis*
Pyridinium Compounds / chemistry*

Substances

Glycosides
Monosaccharides
N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-glucopyranosyl)pyridinium chloride
Pyridinium Compounds