Luminescent photoproducts in UV-irradiated ice

Acc Chem Res. 2000 Oct;33(10):665-71. doi: 10.1021/ar990145e.

Abstract

This Account describes the near-UV and visible luminescences emitted from crystalline, polycrystalline, and amorphous ices as a result of excitation by UV light. Vibrationally resolved, short-lived luminescence around 340 nm arises from excited O(2) formed by the reaction of two O atoms. Long-lived luminescence around 420 nm is tentatively assigned to a spin-forbidden (4)sigma(-) --> X(2)Pi transition of OH. This Account gives a history of the research into this little-known phenomenon, places it in the context of other spectroscopic studies of gaseous and solid water, and proposes future directions for the work.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ice*
  • Luminescent Measurements
  • Ultraviolet Rays*

Substances

  • Ice