Dynamic surface tension and adsorption mechanisms of surfactants at the air-water interface

Adv Colloid Interface Sci. 2000 Mar 31;85(2-3):103-44. doi: 10.1016/s0001-8686(99)00017-2.

Abstract

Recent advances in understanding dynamic surface tensions (DSTs) of surfactant solutions are discussed. For pre-CMC solutions of non-ionic surfactants, theoretical models and experimental evidence for a mixed diffusion-kinetic adsorption mechanism are covered. For micellar solutions of non-ionics, up to approximately 100 x CMC, the DST behaviour can also be accounted for using a mixed mechanism model. Finally, the first reported measurements of the dynamic surface excess Gamma(t), using the overflowing cylinder in conjunction with neutron reflection, are described.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Adsorption
  • Air
  • Diffusion
  • Edetic Acid / pharmacology
  • Electrolytes / pharmacology
  • Kinetics
  • Micelles
  • Models, Chemical
  • Neutrons
  • Osmolar Concentration
  • Surface Tension
  • Surface-Active Agents / chemistry*
  • Temperature
  • Thermodynamics
  • Water
  • Wettability

Substances

  • Electrolytes
  • Micelles
  • Surface-Active Agents
  • Water
  • Edetic Acid