Presence of 2-furoylmethyl derivatives in hydrolysates of processed tomato products

J Agric Food Chem. 2000 Feb;48(2):468-71. doi: 10.1021/jf990697b.

Abstract

Acid hydrolysis of Amadori compounds yields the corresponding 2-furoylmethylamino acids (2-FM-AA) that can be analyzed by ion-pair HPLC. The relative proportions of the different 2-FM-AA present in the hydrolysates of tomato products were determined to assess their usefulness as indicators of quality. In the lyophilized tomato samples stored at 50 degrees C and a(w) = 0.44 the formation of 2-FM derivatives of alanine, gamma-aminobutyric acid (GABA), asparagine, aspartic acid, glutamic acid, lysine, serine, and threonine was detected. In commercial tomato products the most abundant 2-FM-AA was 2-FM-GABA (from traces to 26.4 mg/100 g of dry matter) followed by 2-FM-lysine (furosine). Differences in 2-FM-AA contents among samples may be related to processing and storage conditions.

MeSH terms

  • Alanine / chemistry
  • Asparagine / chemistry
  • Aspartic Acid / chemistry
  • Chromatography, High Pressure Liquid
  • Freeze Drying
  • Furans / chemistry*
  • Glutamic Acid / chemistry
  • Hydrolysis
  • Lysine / chemistry
  • Maillard Reaction
  • Serine / chemistry
  • Solanum lycopersicum / metabolism*
  • Threonine / chemistry
  • gamma-Aminobutyric Acid / chemistry

Substances

  • Furans
  • Threonine
  • Aspartic Acid
  • Glutamic Acid
  • Serine
  • gamma-Aminobutyric Acid
  • Asparagine
  • Lysine
  • Alanine