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Properties of the iron-sulfur cluster electron transfer relay in an [FeFe]-hydrogenase that is tuned for H2 oxidation catalysis.
J Biol Chem. 2024 Apr 16;300(6):107292. doi: 10.1016/j.jbc.2024.107292. Online ahead of print.
J Biol Chem. 2024.
PMID: 38636659
Free PMC article.
Characterization of ferredoxins involved in electron transfer pathways for nitrogen fixation implicates differences in electronic structure in tuning 2[4Fe4S] Fd activity.
Lewis NM, Kisgeropoulos EC, Lubner CE, Fixen KR.
Lewis NM, et al. Among authors: kisgeropoulos ec.
J Inorg Biochem. 2024 May;254:112521. doi: 10.1016/j.jinorgbio.2024.112521. Epub 2024 Mar 7.
J Inorg Biochem. 2024.
PMID: 38471286
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The Contribution of Proton-Donor pKa on Reactivity Profiles of [FeFe]-hydrogenases.
Kisgeropoulos EC, Bharadwaj VS, Mulder DW, King PW.
Kisgeropoulos EC, et al.
Front Microbiol. 2022 Sep 28;13:903951. doi: 10.3389/fmicb.2022.903951. eCollection 2022.
Front Microbiol. 2022.
PMID: 36246213
Free PMC article.
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Pulsed Multifrequency Electron Paramagnetic Resonance Spectroscopy Reveals Key Branch Points for One- vs Two-Electron Reactivity in Mn/Fe Proteins.
Kisgeropoulos EC, Gan YJ, Greer SM, Hazel JM, Shafaat HS.
Kisgeropoulos EC, et al.
J Am Chem Soc. 2022 Jul 13;144(27):11991-12006. doi: 10.1021/jacs.1c13738. Epub 2022 Jul 5.
J Am Chem Soc. 2022.
PMID: 35786920
Free PMC article.
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Ligand Field Inversion as a Mechanism to Gate Bioorganometallic Reactivity: Investigating a Biochemical Model of Acetyl CoA Synthase Using Spectroscopy and Computation.
Kisgeropoulos EC, Manesis AC, Shafaat HS.
Kisgeropoulos EC, et al.
J Am Chem Soc. 2021 Jan 20;143(2):849-867. doi: 10.1021/jacs.0c10135. Epub 2021 Jan 8.
J Am Chem Soc. 2021.
PMID: 33415980
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Key Structural Motifs Balance Metal Binding and Oxidative Reactivity in a Heterobimetallic Mn/Fe Protein.
Kisgeropoulos EC, Griese JJ, Smith ZR, Branca RMM, Schneider CR, Högbom M, Shafaat HS.
Kisgeropoulos EC, et al.
J Am Chem Soc. 2020 Mar 18;142(11):5338-5354. doi: 10.1021/jacs.0c00333. Epub 2020 Mar 9.
J Am Chem Soc. 2020.
PMID: 32062969
Free PMC article.
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